WebEnergy levels are placed relative to the vacuum level by photoemission spectroscopy, which provides a measure of the work function and electron affinity of the investigated BiVO4 thin film. The implications of the fundamental electronic structure of ms-BiVO4 on its photocatalytic behavior, as well as considerations for improvements by ... WebJul 5, 2024 · In this work, we show that phase-pure, monoclinic BiVO4 nanoislands with a truncated pyramid shape displaying {110} sidewalls can be grown on (001)-oriented yttria-stabilized zirconia (YSZ) substrates with an epitaxial relationship of BiVO4(010)[001] // …
The role of surface oxygen vacancies in BiVO4 - NSF
WebFergusonite-type monoclinic BiVO4 (fm-BiVO4) is an important semiconductor photocatalyst as an alternative to TiO2 for solar energy conversion and environmental protection. Based upon density functional theory (DFT) calculations, we report the results of a comprehensive study of the surface properties of fm-BiVO4, ... The work function ... WebMar 31, 2024 · The 2-electron water oxidation reaction (WOR) for H 2 O 2 production has been examined over many metal oxides, such as ZnO, [] Bi 2 WO 6, [] TiO 2, [] BiVO 4, [7, 8] etc. Among these oxides, BiVO 4 is the most promising photoanode for 2-electron WOR due to its suitable bandgap for light-harvesting, deep valance band edge, and favorable … philips hd7865 60 test
Tailored BiVO4 Photoanode Hydrophobic Microenvironment …
WebAug 9, 2016 · When the Bi 4 V 2 O 11 containing dipole moments is brought into intimate contact with the BiVO 4, it is the difference between the effective work functions of the two that is the driving force ... WebBiVO4 (BVO) is a promising photoanode material for photoelectrochemical (PEC) water splitting. However, it is severely restricted by its short charge diffusion length and poor … WebFeb 27, 2024 · Thus, the tunability of the Fermi level position within BiVO4 seems to be limited to a certain range. The feasibility of high upwards band bending through junctions with high work function (WF) compounds demonstrate that nickel oxide and cobalt oxide are able to enhance the charge carrier separation in BiVO4. philips hd7865